Apparently, glutathionylation of the two class I GRXs by GSSG occurs even at very low GSSG amounts in freshly prepared GSH due to binding of GSSG in a way that favours a trigonal planar bipyramidal transition state 13,15
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Inhibition of the EMT by sulforaphane in thyroid cancer cells has been associated with upregulation of an epithelial marker, E-cadherin, and downregulation of a transcription factor (SNAI2), a filament protein (vimentin), and various enzymes (matrix metalloprotein [MMP]-2 and MMP-9) known to contribute to EMT and promote migration (32)
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